(silver) Alexandre Tuffère
1896 triple jump
(silver) Charles Poulenard (middle name Alexandre)
1912 4x400 m relay
(silver) Jean Bouin (a.k.a. Alexandre)
1912 5000 m
(silver) René Mourlon (middle name Alexandre)
1920 4x100 m relay
(bronze) Alexandre Gemignani
1948 basketball
(bronze) Alexandre Jany
1948; 1952 swimming - 4x200 m freestyle relay
(silver) Alexandre Despatie
2004; 2008 diving - springboard
(bronze/silver) Alexandre Pato
2008; 2012 football
(gold) Alexandre Bilodeau
2010; 2014 freestyle skiing