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Doña María Tomasa Palafox y Portocarrero, Marquise of Villafranca and Duchess of Medina Sidonia (1780–1835), was a Spanish noblewoman. She was a patron and muse of the painter Francisco de Goya y Lucientes and the wife of Francisco de Borja Álvarez de Toledo, 12th Marquis of Villafranca.
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