(bronze) Silvia Chivás Baró
1972 100 m; 4x100 m relay

(silver) Silvia Poll Ahrens
1988 swimming - 200 m freestyle

(silver/bronze) Sílvia Andrea Santos Luz
1996; 2000 basketball

(gold) Silvia Bosurgi
2004 water polo

(bronze) Silvia Navarro
2012 handball

(silver) Silvia Domínguez
2016 basketball
