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It was always my impression that the region in southern Italy got its name from Greek settlers and not the Romans; the Greek word for light gives us words like phosphorus and photograph, so there wouldn't be a connection there.

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Once more, I can't prove this - but my guess would be that the luc- is the same as the lyc- in, for instance, lycanthropy and that Lucania was therefore named after the wolves that would have lived there.

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I'm sure someone on this board will be better informed than me! Sooner or later the answer will appear ...

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All the best

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